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Atom Transfer Radical Polymerization with Ti(III) Halides and Alkoxides

โœ Scribed by Yuri A. Kabachii; Sergei Y. Kochev; Lyudmila M. Bronstein; Inna B. Blagodatskikh; Peter M. Valetsky


Book ID
106000687
Publisher
Springer
Year
2003
Tongue
English
Weight
564 KB
Volume
50
Category
Article
ISSN
0170-0839

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๐Ÿ“œ SIMILAR VOLUMES


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## Abstract Copperโ€mediated atom transfer radical polymerization (ATRP) is versatile for living polymerizations of a wide range of monomers, but ATRP of vinyl acetate (VAc) remains challenging due to the low homolytic cleavage activity of the carbonโ€halide bond of the dormant poly(vinyl acetate) (P

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## Abstract The iron(III)โ€catalyzed atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was successfully employed using tributylphosphine (TBP) and trimethylphosphite (TMP) as ligands in the absence of a reducing agent. The effects of solvent and initiator on polymerization of