Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid
✍ Scribed by Sebastien Maria; Tadeusz Biedroń; Rinaldo Poli; Przemysaw Kubisa
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 113 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0021-8995
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## Abstract The kinetics of methyl methacrylate (MMA) homopolymerization performed by atom transfer radical polymerization (ATRP) is investigated in detail using ethyl‐2‐bromopropionate (EPN‐Br) as initiator, CuBr as catalyst, and pentamethyldiethylenetriamine (PMDETA) as ligand in ionic liquids (I
## Abstract Three novel iniferter reagents were synthesized and used as initiators for the polymerizations of methyl methacrylate (MMA) and styrene (St) in the presence of copper(I) bromide and __N,N,N__′,__N__″,__N__″‐pentamethyldiethylenetriamine at 90 and 115°C, respectively. All the polymerizat