## Abstract **Summary:** The living polymerization of __N__,__N__‐dimethylacrylamide was achieved by atom transfer radical polymerization catalyzed by copper chloride complexed with a new ligand, __N__,__N′__‐bis(pyridin‐2‐ylmethyl 3‐hexoxo‐3‐oxopropyl)ethane‐1,2‐diamine (BPED). With methyl 2‐chlor
Atom Transfer Radical Polymerization of N,N -Dimethylacrylamide
✍ Scribed by Rademacher, Jude T.; Baum, Marina; Pallack, Mical E.; Brittain, William J.; Simonsick, William J.
- Book ID
- 121307026
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 96 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0024-9297
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📜 SIMILAR VOLUMES
## Abstract **Summary:** Controlled polymerization of __N__‐isopropylacrylamide (NIPAAM) was achieved by atom transfer radical polymerization (ATRP) using ethyl 2‐chloropropionate (ECP) as initiator and CuCl/tris(2‐dimethylaminoethyl)amine (Me~6~TREN) as a catalytic system. The polymerization was c
## Abstract ATRP of 2‐(__N,N__‐dimethylamino)ethyl acrylate (DMAEA) was investigated using CuBr or CuCl with different multidentate ligands. The catalyst was found active for DMAEA polymerization when ligated with tris[2‐(__N,N__‐dimethylamino)ethyl]amine. Good control over molecular weight was ach