## Abstract **Summary:** The living polymerization of __N__,__N__‐dimethylacrylamide was achieved by atom transfer radical polymerization catalyzed by copper chloride complexed with a new ligand, __N__,__N′__‐bis(pyridin‐2‐ylmethyl 3‐hexoxo‐3‐oxopropyl)ethane‐1,2‐diamine (BPED). With methyl 2‐chlor
The free radical polymerization of N,N-dimethylacrylamide
✍ Scribed by A.M. North; A.M. Scallan
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 390 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0032-3861
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Two possible crosslinking mechanisms of PNVF gels. Scheme 1. Polymerization of NVF and hydrolysis of PNVF to PVAm.
## Abstract **Summary:** The first example of a room temperature reversible addition‐fragmentation chain transfer polymerization conducted directly in aqueous media is detailed. Under these conditions acrylamide and __N__,__N__‐dimethylacrylamide may be polymerized in a controlled fashion to near q
The reactions of N-vinylcarbazole and of N-vinylpyrrolidone with benzoyl peroxide and with di-t-butyl peroxalate in the presence of the nitroxide scavenger l,l,3,3-tetramethyl-l,3-dihydroisoindol-2yloxyl are reported. Use of di-t-butyl peroxalate leads to the expected radical intermediates which are