The free radical and anionic polymerization of some N-substituted maleimides
β Scribed by R.C.P. Cubbon
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- English
- Weight
- 401 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0032-3861
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π SIMILAR VOLUMES
## Abstract The kinetic feature of the anionic polymerization of __N__βPMI was investigated in THF. The polymerization system initiated with lithium __tert__βbutoxide was revealed to be soβcalled βslowβinitiationβ system. The rate constant of the initiation reaction, __k__~__i__~, was obtained to b
Asymmetric anionic homopolymerizations of achiral N-substituted maleimides (RMI) were performed with lithium 4-alkyl-2,2-dialkyloxazolidinylamide. All obtained polymers were optically active, exhibiting opposite optical rotation to that of a corresponding oxazolidinyl group at the terminal of the ma