## Abstract **Summary:** The living polymerization of __N__,__N__‐dimethylacrylamide was achieved by atom transfer radical polymerization catalyzed by copper chloride complexed with a new ligand, __N__,__N′__‐bis(pyridin‐2‐ylmethyl 3‐hexoxo‐3‐oxopropyl)ethane‐1,2‐diamine (BPED). With methyl 2‐chlor
✦ LIBER ✦
Copolymerization of N , N -Dimethylacrylamide with n -Butyl Acrylate via Atom Transfer Radical Polymerization
✍ Scribed by Neugebauer, Dorota; Matyjaszewski, Krzysztof
- Book ID
- 127258621
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 148 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0024-9297
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## Abstract ATRP of 2‐(__N,N__‐dimethylamino)ethyl acrylate (DMAEA) was investigated using CuBr or CuCl with different multidentate ligands. The catalyst was found active for DMAEA polymerization when ligated with tris[2‐(__N,N__‐dimethylamino)ethyl]amine. Good control over molecular weight was ach