Atmospheric Chemistry of Fluorinated Alcohols: Reaction with Cl Atoms and OH Radicals and Atmospheric Lifetimes
β Scribed by Hurley, M. D.; Wallington, T. J.; Sulbaek Andersen, M. P.; Ellis, D. A.; Martin, J. W.; Mabury, S. A.
- Book ID
- 126116698
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 111 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 Β± 0.7) Γ 10^β13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 Β± 0.8) Γ 10^β15^ (in un
Rate constants for the reactions of C1 atoms and OH radicals with haloalkanes were measured using the relative rate technique. From these values the atmospheric lifetimes of the organics with respect to C1 atoms and OH radicals were calculated. C1 atoms were produced by the photolysis of chlorine ga