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Atmospheric Chemistry of Perfluorinated Carboxylic Acids: Reaction with OH Radicals and Atmospheric Lifetimes

✍ Scribed by Hurley, M. D.; Sulbaek Andersen, M. P.; Wallington, T. J.; Ellis, D. A.; Martin, J. W.; Mabury, S. A.

Book ID: 120662426
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 90 KB
Volume: 108
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp036343b

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A relative rate technique has been used to study the title reaction over the pressure range 100-700 Torr of air at 296 + 2 K. Four different reference compounds (13CO, CH4, CH2FCI, and CD 4) were used. Using k(CF30 + CH 4) = (2.2 -1-0.2) × 10-14 cm 3 molecule-1 s-1 a rate constant of k(CF30 + 03) =