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Asymmetric Synthesis of Tertiary Benzylic Alcohols

✍ Scribed by Antczak, Monika I.; Cai, Feng; Ready, Joseph M.

Book ID
118241015
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
897 KB
Volume
13
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Asymmetric Synthesi
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## Abstract Vinyl, aryl, and alkynyl organometallics add to ketones containing a stereogenic sulfoxide to give tertiary alcohols in diastereo‐ and enantiomerically pure form such as (III) or (VII).

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Pseudourea-Mediated Dehydration of Tertiary and Benzylic Alcohols. -An efficient method for the dehydration of benzylic or tertiary alcohols is presented involving the copper-catalyzed formation of a pseudourea intermediate from alcohol and dicyclohexylcarbodiimide which undergoes subsequently elim