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Asymmetric Synthesis of Corsifuran A by an Enantioselective Oxazaborolidine Reduction †

✍ Scribed by Adams, Harry; Gilmore, Nathan J.; Jones, Simon; Muldowney, Mark P.; von Reuss, Stephan H.; Vemula, Ramesh

Book ID
119992500
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
76 KB
Volume
10
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis of Corsifuran A by an Enantioselective Oxazaborolidine Reduction.
✍ Harry Adams; Nathan J. Gilmore; Simon Jones; Mark P. Muldowney; Stephan H. von R 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 16 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Synthesis of Ro 25-8210 via an enantiose
Synthesis of Ro 25-8210 via an enantioselective oxazaborolidine-catalyzed reduction
✍ Kenneth G. Hull; Mike Visnick; William Tautz; Allen Sheffron 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 552 KB

Prochiral ketones which contain nitrogen atoms have been reduced enantioselectively with chiral oxazaborolidines in the presence of excess borane. However, the pyridine system has been shown to be a poor substrate for this asymmetric reduction. For example, catalytic reduction of 2acetylpyridine wit