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Asymmetric synthesis of (−)-bissetone via a highly enantioselective hetero-Diels–Alder reaction

✍ Scribed by Majer, Jakub; Jurczak, Janusz; Kwiatkowski, Piotr; Cotarca, Livius; Caille, Jean-Claude

Book ID
120808209
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
565 KB
Volume
69
Category
Article
ISSN
0040-4020

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AbstractÐA formal asymmetric synthesis of (2)-epibatidine is reported. The key step of the synthesis is a regio-and diastereoselective cycloaddition of silyloxycyclohexadiene with the acylnitroso dienophile derived from (1)-camphorsultam. The resulting cycloadduct was readily transformed into the N-