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Asymmetric synthesis of arylselenoalcohols by means of the reduction of organoseleno acetophenones by whole fungal cells

✍ Scribed by Leandro H. Andrade; Álvaro T. Omori; André L.M. Porto; João V. Comasseto

Book ID
113803791
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
123 KB
Volume
29
Category
Article
ISSN
1381-1177

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Stereoselective Synthesis of Sphinganine by Means of Modified Asymmetric Borane Reduction. -A modified asymmetric borane reduction of the ester (I) and the related silyl ether (V) are described. Thus, reduction of the ester yields mainly the threo compound, whereas the silyl ether affords the desir