𝔖 Bobbio Scriptorium
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Asymmetric Synthesis. Kinetic Amplification of Enantiomeric Excess

✍ Scribed by Bergens, Steven; Bosnich, B.

Book ID
120442618
Publisher
Taylor and Francis Group
Year
1987
Tongue
English
Weight
234 KB
Volume
6
Category
Article
ISSN
0260-3594

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πŸ“œ SIMILAR VOLUMES

One-pot asymmetric autocatalytic reactio
One-pot asymmetric autocatalytic reaction with remarkable amplification of enantiomeric excess
✍ Takanori Shibata; Tadakatsu Hayase; Jun Yamamoto; Kenso Soai πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 157 KB

A trace amount (ca. 3 mg) of 2-methylpyrimidyl alkanol with only a slight enantiomeric excess (0.2-0.3% e.e.) was auto-multiplied with dramatic amplification of enantiomeric excess (up to ca. 90% e.e.) in one-pot asymmetric autocatalytic reaction using diisopropylzinc and 2-methylpyrimidine-5-carbal

Relationship between the time, yield, an
Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess
✍ Itaru Sato; Daisuke Omiya; Hiroyoshi Igarashi; Keiichi Kato; Yoshihiro Ogi; Koic πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 174 KB

Experimental and kinetic analysis of asymmetric autocatalysis with amplification of ee in the enantioselective addition of diisopropylzinc to 2-alkynylpyrimidine-5-carbaldehyde using chiral 2-alkynyl-5-pyrimidyl alkanol with low ee's are described.