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One-pot asymmetric autocatalytic reaction with remarkable amplification of enantiomeric excess

✍ Scribed by Takanori Shibata; Tadakatsu Hayase; Jun Yamamoto; Kenso Soai

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 157 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(97)00183-3

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✦ Synopsis

A trace amount (ca. 3 mg) of 2-methylpyrimidyl alkanol with only a slight enantiomeric excess (0.2-0.3% e.e.) was auto-multiplied with dramatic amplification of enantiomeric excess (up to ca. 90% e.e.) in one-pot asymmetric autocatalytic reaction using diisopropylzinc and 2-methylpyrimidine-5-carbaldehyde.

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