✦ LIBER ✦

Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess

✍ Scribed by Itaru Sato; Daisuke Omiya; Hiroyoshi Igarashi; Keiichi Kato; Yoshihiro Ogi; Koichi Tsukiyama; Kenso Soai

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 174 KB
Volume: 14
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(03)00164-2

No coin nor oath required. For personal study only.

✦ Synopsis

Experimental and kinetic analysis of asymmetric autocatalysis with amplification of ee in the enantioselective addition of diisopropylzinc to 2-alkynylpyrimidine-5-carbaldehyde using chiral 2-alkynyl-5-pyrimidyl alkanol with low ee's are described.

📜 SIMILAR VOLUMES

Highly enantioselective asymmetric autoc

Highly enantioselective asymmetric autocatalysis of 2-alkenyl- and 2-vinyl-5-pyrimidyl alkanols with significant amplification of enantiomeric excess

✍ Itaru Sato; Tomotaka Yanagi; Kenso Soai 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 70 KB

ChemInform Abstract: Asymmetric Autocata

ChemInform Abstract: Asymmetric Autocatalysis of 5-Carbamoyl-3-pyridyl Alkanols with Amplification of Enantiomeric Excess.

✍ Shigehisa Tanji; Yasutaka Kodaka; Atsushi Ohno; Takanori Shibata; Itaru Sato; Ke 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 32 KB