A novel reaction system is described for the complete stereoselective addition of carbanionic nucleophiles to ,+hydroxy ketones. Controlling l,n-asymmetric induction in nucleophilic addition to acyclic carbonyl compounds is one of the most powerful and useful synthetic methods in organic chemistry.
β¦ LIBER β¦
Asymmetric synthesis based on 1,3-oxathianes. 4. Mechanism of asymmetric induction in the reactions of oxathianyl ketones
β Scribed by Frye, Stephen V.; Eliel, Ernest L.
- Book ID
- 126325568
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 957 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0002-7863
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