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1,4-Asymmetric induction in the titanium-mediated aldol reactions of α-benzyloxy methyl ketones

✍ Scribed by Miquel Pellicena; Joan G. Solsona; Pedro Romea; Fèlix Urpí

Book ID
108285093
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
171 KB
Volume
49
Category
Article
ISSN
0040-4039

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1,4-syn-Asymmetric induction in the tita
1,4-syn-Asymmetric induction in the titanium-mediated aldol reactions of chiral methyl α-silyloxy ketones
✍ Adriana Lorente; Miquel Pellicena; Pedro Romea; Fèlix Urpí 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 300 KB

Good levels of 1,4-syn asymmetric induction are obtained in the TiCl 4 -mediated aldol reaction of methyl a-silyloxy ketones with achiral aldehydes. Such methodology represents a new approach to the substrate-controlled acetate aldol reaction, which can be useful to design more efficient syntheses o