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Asymmetric Syntheses of Derivatives of β- and γ-Aryl and α-Alkyl Amino Acids Using n -BuLi/(−)-Sparteine

✍ Scribed by Kim, Bong Jin; Park, Yong Sun; Beak, Peter


Book ID
118742248
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
61 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Asymmetric Synthese
✍ Bong Jin Kim; Yong Sun Park; Peter Beak 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

Asymmetric Syntheses of Derivatives of β-and γ-Aryl and α-Alkyl Amino Acids Using n-BuLi/(-)-Sparteine. -Alkylation of N-Boc and N-arylmethyl or N-cinnamyl p-anisidines with BuLi/(-)-sparteine allows the efficient synthesis of highly enantioenriched derivatives which can be transformed into a varie