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Asymmetric oxidation of sulfenyl substituted tricarbonyl(η6-arene)chromium(0) complexes

✍ Scribed by Siân L. Griffiths; Stéphane Perrio; Susan E. Thomas

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
283 KB
Volume
5
Category
Article
ISSN
0957-4166

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✦ Synopsis

Oxidation of sulfenyl substituted tricarbonyl(ll6-arene)chrom(o) complexes with Ti(OP& I diethyl lartraw I H20 I cumene hydroperoxide (2:4:2:1.3) gives sulfinyl suhstitured tricarbonyl(q6arcne)chromium(O) complexes in 60.73% yield and 111.86% e.e. (29.60% yield and 90.t95t c e. after cryslallisation); dietbyl L-(+)-tartrate was shown 10 lead 10 complexes of R contiguration.

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