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Asymmetric induction in the nucleophile addition to η6-arene-tricarbonyl-chromium(0) complexes

✍ Scribed by M.F Semmelhack; Hans-Günther Schmalz

Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 225 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(96)00572-2

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In Table 1, entry 17 should read 74% e.e., entry 18 (71% e.e.), entry 14 (n/d), and entry 19 (47% e.e.) using 0.05 equiv. of PdCl(h 3 -C 3 H 5 ). Product yields reported (Scheme 2) are based on recovered alkene substrates. Complete hydrosilylation (assessed initially by NMR analysis of derived metho