Corrigendum to “Bidentate planar chiral η6-arene tricarbonyl chromium(0) complexes: ligands for catalytic asymmetric alkene hydrosilylation”: [Tetrahedron Lett. 42 (2001) 6983–6986]

✍ Scribed by Immo Weber; Graham B. Jones

• Publisher: Elsevier Science
• Year: 2002
• Tongue: French
• Weight: 31 KB
• Volume: 43
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(02)00060-6

✦ Synopsis

In Table 1, entry 17 should read 74% e.e., entry 18 (71% e.e.), entry 14 (n/d), and entry 19 (47% e.e.) using 0.05 equiv. of PdCl(h 3 -C 3 H 5 ). Product yields reported (Scheme 2) are based on recovered alkene substrates. Complete hydrosilylation (assessed initially by NMR analysis of derived methoxysilane adducts) varies from 2 min to >14 days and appears to be influenced by subtle changes in initial reagent mixing temperature; complete details will be reported in a full account of this work.