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Asymmetric Michael Addition of α-Hydroxyketones to Nitroolefins Catalyzed by Chiral Diamine

✍ Scribed by Andrey, Olivier; Alexakis, Alexandre; Bernardinelli, Gérald

Book ID
126305286
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
57 KB
Volume
5
Category
Article
ISSN
1523-7060

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A Chiral Functionalized Salt-Catalyzed A
A Chiral Functionalized Salt-Catalyzed Asymmetric Michael Addition of Ketones to Nitroolefins
✍ Yan Xiong; Yuehong Wen; Fei Wang; Bo Gao; Xiaohua Liu; Xiao Huang; Xiaoming Feng 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 278 KB 👁 2 views

## Abstract The chiral functionalized salt catalysis, which differs from the known enzyme‐ and transition metal‐based methods, has been successfully developed to carry out the Michael addition of ketones to nitroolefins. Chiral anion salt (type **I**), chiral cation salt (type **II**), or chiral an