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Asymmetric Michael Addition of α-Hydroxyketones to Nitroolefins Catalyzed by Chiral Diamine.

✍ Scribed by Olivier Andrey; Alexandre Alexakis; Gerald Bernardinelli

Publisher
John Wiley and Sons
Year
2003
Weight
117 KB
Volume
34
Category
Article
ISSN
0931-7597

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A Chiral Functionalized Salt-Catalyzed A
A Chiral Functionalized Salt-Catalyzed Asymmetric Michael Addition of Ketones to Nitroolefins
✍ Yan Xiong; Yuehong Wen; Fei Wang; Bo Gao; Xiaohua Liu; Xiao Huang; Xiaoming Feng 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 278 KB 👁 2 views

## Abstract The chiral functionalized salt catalysis, which differs from the known enzyme‐ and transition metal‐based methods, has been successfully developed to carry out the Michael addition of ketones to nitroolefins. Chiral anion salt (type **I**), chiral cation salt (type **II**), or chiral an