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Asymmetric Induction in the Electrochemical Cross-Coupling of Aryl Halides with α-Chloropropionic Acid Derivatives Catalyzed by Nickel Complexes

✍ Scribed by Durandetti, Muriel; Périchon, Jacques; Nédélec, Jean-Yves


Book ID
118155681
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
81 KB
Volume
62
Category
Article
ISSN
0022-3263

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The arylboronic acids 2 and 4 derived by directed ortho metalation of benzamides and carbamates, undergo an efficient palladium-catalyzed cross coupling reaction with a variety of aryl halides to yield unsymmetrical biaryls and heterobiaryls (Table ).