✦ LIBER ✦

Asymmetric hydrogenation of activated keto compounds catalyzed by new chiral peralkyl-ampp rhodium complexes

✍ Scribed by Corinne Hatat; Abdallah Karim; Nicolas Kokel; André Mortreux; Francis Petit

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 164 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82151-6

No coin nor oath required. For personal study only.

✦ Synopsis

Readily available peralkyl aminophosphinephosphinite ligands (alkyl-AMPP*) give neutral rhodium complexes active for the catalytic reduction of some activated ketones under atmospheric hydrogen pressure at ambient temperature (ee = 80 %).

Asymmetric hydrogenation of ketones has been performed under rather drastic conditions on rhodium diphosphine catalysts in moderate optical yieldsl.

📜 SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Hydrogen

ChemInform Abstract: Asymmetric Hydrogenation of α, β, and γ-Aminoketones Catalyzed by Cationic Rhodium(I){AMPP} Complexes.

✍ M. DEVOCELLE; F. AGBOSSOU; A. MORTREUX 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

The mechanism of asymmetric hydrogenatio

The mechanism of asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes

✍ Kazuo Achiwa; Yoko Ohga; Yoichi Iitaka; Hazime Saito 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 225 KB

Effective catalytic asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes have been proven to be useful for the preparation of optically active a-amino acids @3-91%)2'3), isoquinoline salsolidine (45%)6) cc-hydroxy esters (78.5%)4'5), R-(-)-pantolactone C80.5-86.7%17'g

Asymmetric synthesis of dipeptides by me

Asymmetric synthesis of dipeptides by means of homogeneous hydrogenation catalyzed by chiral rhodium complexes

✍ Iwao Ojima; Tadashi Suzuki 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 191 KB

Synthesis of new chiral arene ruthenium(

Synthesis of new chiral arene ruthenium(II) aminophosphinephosphinite complexes and use in asymmetric hydrogenation of an activated keto compound

✍ Frédéric Hapiot; Francine Agbossou; André Mortreux 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 332 KB

Asymmetric hydrogenation of enol phosphi

Asymmetric hydrogenation of enol phosphinates catalyzed by a chiral ferrocenylphosphine-rhodium complex. Asymmetric synthesis of optically active secondary alkyl alcohols

✍ Tarnio Hayashi; Koichi Kanehira; Makoto Kumada 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 273 KB

Enantioselective Hydrogenation Catalyzed

Enantioselective Hydrogenation Catalyzed by Highly Active Rhodium Complexes of Chiral Phosphites with Atropisomeric Moieties.

✍ Ildiko Gergely; Csaba Hegedues; Henrik Gulyas; Aron Szoelosy; Axel Monsees; Thom 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 94 KB