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Asymmetric hydrogenation of enol phosphinates catalyzed by a chiral ferrocenylphosphine-rhodium complex. Asymmetric synthesis of optically active secondary alkyl alcohols

โœ Scribed by Tarnio Hayashi; Koichi Kanehira; Makoto Kumada


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
273 KB
Volume
22
Category
Article
ISSN
0040-4039

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Asymmetric hydrosilylation of olefins ca
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swmnary : Optically active norbornyl and l-phenylethyl alcohols and bromides were obtained, res- pectively, from norbornyl-and l-phenylethylpentafluorosilicates which were prepared by asymmetric hydrosilylation of norbornene and styrene with trichlorosilane catalyzed by a chiral ferrocenylphosphine-