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Enantioselective Hydrogenation Catalyzed by Highly Active Rhodium Complexes of Chiral Phosphites with Atropisomeric Moieties.

✍ Scribed by Ildiko Gergely; Csaba Hegedues; Henrik Gulyas; Aron Szoelosy; Axel Monsees; Thomas Riermeier; Jozsef Bakos


Publisher
John Wiley and Sons
Year
2003
Weight
94 KB
Volume
34
Category
Article
ISSN
0931-7597

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Highly Enantioselective Hydrogenation of
✍ M. Ángeles Chávez; Sergio Vargas; Andrés Suárez; Eleuterio Álvarez; Antonio Pizz 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 671 KB

## Abstract The enantioselective hydrogenation of β‐(acyloxy)‐ and β‐(acylamino)vinylphosphonates with rhodium catalysts based on chiral phosphane‐phosphite ligands has been studied. In the case of the β‐(acyloxy)vinylphosphonates, the reaction also produces an achiral phosphonate resulting from th