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Asymmetric hydrogenation catalyzed by a chiral ferrocenylphosphine-rhodium complex

โœ Scribed by Tamio Hayashi; Takaya Mise; Seiko Mitachi; Keiji Yamamoto; Makoto Kumada


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
120 KB
Volume
17
Category
Article
ISSN
0040-4039

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## Abstract A novel chelated ferroceneโ€based planar chiral Nโ€heterocyclic carbeneโ€Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright ยฉ 2009 John Wiley & Sons, L