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Asymmetric Hydroformylation of Olefins with Rh Catalysts Modified with Chiral Phosphine−Phosphite Ligands

✍ Scribed by Rubio, Miguel; Suárez, Andrés; Álvarez, Eleuterio; Bianchini, Claudio; Oberhauser, Werner; Peruzzini, Maurizio; Pizzano, Antonio


Book ID
111969395
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
358 KB
Volume
26
Category
Article
ISSN
0276-7333

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Asymmetric hydroformylation of conjugate
✍ Toshihide Horiuchi; Tetsuo Ohta; Eiji Shirakawa; Kyoko Nozaki; Hidemasa Takaya 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 503 KB

Asymmetric hydroformylation of conjugated dienes has been investigated using (R,S)-BINAPHOS-Rh(I) complex as a catalyst [(R,S)-BINAPHOS = (R)-2-(diphenylphosphino)-l,l'binaphthalen-2'-yl (S)-I,1 '-binaphthalene-2,2'-diyl phosphite]. Optically active 13,~,-unsaturated aldehydes were obtained in high