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Asymmetric Hetero-Diels—Alder Reactions of Danishefsky′s and Brassard′s Dienes with Aldehydes

✍ Scribed by Lili Lin; Xiaohua Liu; Xiaoming Feng


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ Baoming Ji; Yu Yuan; Kuiling Ding; Jiben Meng 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB

## Abstract A new type of dendritic 2‐amino‐2′‐hydroxy‐1,1′‐binaphthyl (NOBIN)‐derived Schiff‐base ligands have been synthesized and applied to the titanium‐catalyzed hetero‐Diels–Alder reaction of Danishefsky's diene with aldehydes. These reactions afforded the corresponding 2‐substituted 2,3‐dihy