## Abstract A new type of dendritic 2‐amino‐2′‐hydroxy‐1,1′‐binaphthyl (NOBIN)‐derived Schiff‐base ligands have been synthesized and applied to the titanium‐catalyzed hetero‐Diels–Alder reaction of Danishefsky's diene with aldehydes. These reactions afforded the corresponding 2‐substituted 2,3‐dihy
Assembled Dendritic Titanium Catalysts for Enantioselective Hetero-Diels—Alder Reaction of Aldehydes with Danishefsky′s Diene.
✍ Scribed by Baoming Ji; Yu Yuan; Kuiling Ding; Jiben Meng
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 117 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract An efficient catalytic enantioselective hetero‐Diels–Alder reaction of Danishefsky's diene with aldehydes using the magnesium binaphthoxide system has been developed, affording a variety of 2‐substituted 2,3‐dihydro‐4__H__‐pyran‐4‐ones in high yields and with excellent __ee__ values. Th
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