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Asymmetric Cyanosilylation of Ketones Catalyzed by Bifunctional Chiral N-Oxide Titanium Complex Catalysts.

✍ Scribed by Yongcun Shen; Xiaoming Feng; Yan Li; Guolin Zhang; Yaozhong Jiang

Publisher
John Wiley and Sons
Year
2004
Weight
118 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract An efficient and optically active, bifunctional tetraaza ligand (2__S__)‐__N__‐{(1__R__,2__R__)‐2‐[(__S__)‐pyrrolidine‐2‐carboxamido]‐1,2‐diphenylethyl}pyrrolidine‐2‐carboxamide has been developed for the addition of trimethylsilyl cyanide (TMSCN) to ketones. The bifunctional catalyst s