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Asymmetric Cyanosilylation of Ketones Catalyzed by Novel Chiral N,N′-Dioxide Titanium Complexes.

✍ Scribed by Qinghan Li; Xiaohua Liu; Jun Wang; Ke Shen; Xiaoming Feng


Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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The catalytic conjugate addition of nitroalkanes to a,b-unsaturated ketones is one of the most important processes in organic synthesis, [1, 2, 3] since the corresponding products are very useful intermediates for the synthesis of a variety of more elaborate structures, such as amino alkanes, amino