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Asymmetric Conjugate Addition to α-Substituted Enones/Enolate Trapping

✍ Scribed by Germain, Nicolas; Guénée, Laure; Mauduit, Marc; Alexakis, Alexandre


Book ID
121433126
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
601 KB
Volume
16
Category
Article
ISSN
1523-7060

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Enantioselective conjugate addition reactions of alkyl radicals to a 0 -phenylsulfonyl enones are described. A bis-oxazoline-zinc triflate complex proved to be an effective catalyst leading to high enantioselectivities and chemical yields.