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Asymmetric Baylis—Hillman Reactions Promoted by Chiral Imidazolines.

✍ Scribed by Junye Xu; Yanyi Guan; Shihui Yang; Yurui Ng; Guangrong Peh; Choon-Hong Tan

Publisher
John Wiley and Sons
Year
2007
Weight
37 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Yujiro Hayashi; Tomohiro Tamura; Mitsuru Shoji 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 117 KB 👁 1 views

## Abstract A chiral diamine, easily prepared from proline, is an effective, asymmetric organic catalyst for the Baylis–Hillman reaction of aldehydes and methyl vinyl ketone, affording adducts with enantioselectivities up to 75%.