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Asymmetric Addition of Cyanide to β-Nitroalkenes Catalysed by Chiral Salen Complexes of Titanium(IV) and Vanadium(V)

✍ Scribed by North, Michael; Watson, James M.


Book ID
120420472
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
368 KB
Volume
5
Category
Article
ISSN
1867-3880

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The asymmetric addition of trimethylsily
✍ Yuri N Belokon; Brendan Green; Nicolai S Ikonnikov; Michael North; Vitali I Tara 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 217 KB

The use of a bimetallic titanium salen complex as a catalyst for the asymmetric addition of trimethylsilylcyanide to ketones is reported. The cyanohydrin trimethyisilyl ethers are obtained with enantiomeric excesses of up to 72% from reactions carried out at room temperature and atmospheric pressure