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The Asymmetric Addition of Trimethylsilyl Cyanide to Aldehydes Catalyzed by Chiral (Salen)Titanium Complexes

✍ Scribed by Belokon', Yuri N.; Caveda-Cepas, Susana; Green, Brendan; Ikonnikov, Nicolai S.; Khrustalev, Viktor N.; Larichev, Vladimir S.; Moscalenko, Margarita A.; North, Michael; Orizu, Charles; Tararov, Vitali I.

Book ID: 111675117
Publisher: American Chemical Society
Year: 1999
Tongue: English
Weight: 99 KB
Volume: 121
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja984197v

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The use of a bimetallic titanium salen complex as a catalyst for the asymmetric addition of trimethylsilylcyanide to ketones is reported. The cyanohydrin trimethyisilyl ethers are obtained with enantiomeric excesses of up to 72% from reactions carried out at room temperature and atmospheric pressure