Asymmetric 3-aza-cope rearrangements using TiCl4 catalysis
β Scribed by Patrick D Bailey; Michael J Harrison
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 200 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro