## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
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ChemInform Abstract: Studies in N-Amino-3-aza Cope Rearrangements.
β Scribed by Paulo M. C. Gloria; Sundaresan Prabhakar; Ana M. Lobo
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 39 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro