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ChemInform Abstract: Studies in N-Amino-3-aza Cope Rearrangements.

✍ Scribed by Paulo M. C. Gloria; Sundaresan Prabhakar; Ana M. Lobo


Publisher
John Wiley and Sons
Year
2009
Weight
39 KB
Volume
40
Category
Article
ISSN
0931-7597

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The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro