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ChemInform Abstract: Studies in 3-Oxy-Assisted 3-Aza Cope Rearrangements.

✍ Scribed by Mario J. S. Gomes; Lalit Sharma; Sundaresan Prabhakar; Ana M. Lobo; Paulo M. C. Gloria

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Computational Studies on 3-Aza-Cope Rear
Computational Studies on 3-Aza-Cope Rearrangements: Protonation- Induced Switch of Mechanism in the Reaction of Vinylpropargylamine
✍ Rainer F. Winter; Guntram Rauhut πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 192 KB πŸ‘ 2 views

The 3-aza-Cope rearrangements of 3-azoniahexa-1,5-diene (1), 3-azoniahex-1-ene-5-yne (3), and 3-azahex-1-ene-5-yne (5) were investigated up to the coupled-cluster level, CCSD(T), by using a valence triple-zeta basis set. Activation barriers and geometrical parameters of the transition states are pro