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Asymmetric 1,4-additions to μ-menthyloxybutenolides. (part III)1 enantioselective synthesis of (−) eudesmin.

✍ Scribed by Johan F.G.A. Jansen; Ben L. Feringa

Book ID
108381503
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
236 KB
Volume
32
Category
Article
ISSN
0040-4039

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Asymmetric 1,4-additions to γ-menthyloxy
Asymmetric 1,4-additions to γ-menthyloxybutenolides. Enantiospecific synthesis of chiral 1,4-butanediols
✍ Johan F.G.A. Jansen; Ben L. Feringa 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 182 KB

Optically active methyl-substituted butanediols and d/-lactones were prepared from [-menthyloxy-2[5HJ-furanone. Chiral [-menthyloxybutenolides (1) have served as the basis for our novel asymmetric synthesis strategies= due to the excellent stereocontrol by the J-menthyloxy substituent, the easy way