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Assignment of the triplet manifolds of d8 complexes and linear chains via the effects of temperature and magnetic fields on the phosphorescence lifetimes

โœ Scribed by G.A. Crosby; K.R. Kendrick

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
752 KB
Volume
171
Category
Article
ISSN
0010-8545

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โœฆ Synopsis

Characteristics of the electronic excited states of transition-metal complexes are reviewed, Attention is focussed on the experimental means of ~dentifying the orbital natures ef the emitting manifolds. Two new criteria for distinguishing among excited triplet terms are enunciated: (a) the profile of the phosphorescence lifetime vs. the temperature in the range 77-4 K, and (b) the functional dependence of the phosphorescence decay rate on an external

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