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Assignment of the Absolute Configuration of Natural Lentiginosine by Synthesis and Enzymic Assays of Optically Pure (+) and (-)-Enantiomers

โœ Scribed by Brandi, Alberto; Cicchi, Stefano; Cordero, Franca M.; Frignoli, Roberta; Goti, Andrea; Picasso, Sylviane; Vogel, Pierre


Book ID
120215185
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
907 KB
Volume
60
Category
Article
ISSN
0022-3263

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โœ Guoqiang Lin; Aimin Zhang ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

Optically pure dimeric O-demethylmurrayafoline A (1) and its 6,6' -dirnethoxyl analog 2 were synthesized via the resolution of their corresponding camphorsulfonates of the racemates. The absolute configurations of (+)-1, (+)-2 and (-)-I, (-)-2 were assigned as (aR) and (aS), respectively, by the X-r