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Assignment of the 1H and 13C NMR spectra and stereochemical analysis of radical-initiated poly(1-naphthylmethyl acrylate) and poly[2-(1-naphthyl)ethyl acrylate]

✍ Scribed by Apostolos Spyros; Photis Dais; Frank Heatley

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 360 KB
Volume: 195
Category: Article
ISSN: 1022-1352
DOI: 10.1002/macp.1994.021950923

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Resonances in the ^1^H and ^13^C NMR spectra of free‐radical polymerised poly(1‐naphthylmethyl acrylate) (PNMA) and poly[2‐(1‐naphthyl)ethyl acrylate] (PNEA) have been assigned using two‐dimensional techniques. The stereosequence distribution in both polymers obeyed Bernoullian statistics with probabilities of an isotactic diad of 0,43 in PNMA and 0,39 in PNEA.

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