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Assignment of absolute configuration of the α,β-unsaturated γ-methyl-γ-lactone of the annonaceous acetogenins by a simple enzymatic method

✍ Scribed by P. Duret; A.-I. Waechter; B. Figadère; R. Hocquemiller; A. Cavé; C. Piérard; M. Pérès


Book ID
103404471
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
210 KB
Volume
37
Category
Article
ISSN
0040-4039

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The reaction of trialkylstannylmethyllit
✍ Tadashi Sato; Toshihiro Kikuchi; Norio Sootome; Eigoro Murayama 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 224 KB

a,@-Epoxy ketones 2\_, upon treatment with two equivalents of trialkylstannylmethyllithium 1, afforded cyclopropanols 2 as a single product in acyclic system, and a mixture of cyclopropanols 2 and methylene 1,2-diols 2 in cyclic system. Under acidic conditions, the cyclopropanols gave p,y-unsaturate