A novel synthetic method for γ-acetoxy-(E)-α,β-unsaturated esters by the palladium catalyzed regio- and stereoselective acetoxylation of β,γ-unsaturated esters
✍ Scribed by Jiro Tsuji; Kiyomi Sakai; Hideo Nagashima; Isao Shimizu
- Book ID
- 107858328
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 235 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
N-Boc-u-msylsarcosine ethyl ester (3) reacts under neutral conditions either with allylic carbonates or with vinyloxinme in the presence of a catalytic amount of Pd(PPh3) 4 and dppe (5 mol%) to give regio-and stereoselectively the corresponding allylated products $ and 6, respectively. Reductive des
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