In the system BaF 2 /BF 3 /PF 5 /anhydrous hydrogen fluoride (aHF) a compound Ba(BF 4 )(PF 6 ) was isolated and characterized by Raman spectroscopy and X-ray diffraction on the single crystal. Ba(BF 4 )(PF 6 ) crystallizes in a hexagonal P62m space group with a ¼ 10.2251(4) Å, c ¼ 6.1535(4) Å, V ¼ 5
AsF6− and BF4− as counter-anions in 18-crown-6/H3O+ structures
✍ Scribed by H. Selig; H. Sheshinski; S. Cohen; I. Columbus; G. Shoham
- Book ID
- 104150594
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 55 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-1139
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## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__