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Ascorbate mediated copper catalyzed reductive cross–coupling of disulfides with aryl iodides

✍ Scribed by Martinek, Marek; Korf, Michal; Srogl, Jiri


Book ID
121263822
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
514 KB
Volume
46
Category
Article
ISSN
1359-7345

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Efficient Copper-Catalyzed Cross-Couplin
✍ Che-Hung Lin; Yu-Jen Wang; Chin-Fa Lee 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB 👁 1 views

## Abstract A copper‐catalyzed cross‐coupling reaction of alkynes with aryl iodides is described. The system tolerates a broad range of functional groups and enables the use of sterically demanding substrates with only 1.0–2.5 mol‐% of Cu~2~O and 1.0–2.5 mol‐% of xantphos as the catalyst.