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Arylation of phosphoryl-stabilized carbanions with metal π-complexes of aryl chlorides and fluorides

✍ Scribed by Galina A Artamkina; Petr K Sazonov; Irina P Beletskaya

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
83 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The nucleophilic aromatic substitution of halogen in metal arene p-complexes h 6 -(ArF)Cr(CO) 3 and [h 6 -(ArHal)FeCp] + [PF 6 ] -(Hal=F,Cl) with phosphoryl-stabilized carbanions ZCH 2 P(O)(OEt) 2 (Z=COOEt, CN) allows the synthesis of metal p-complexes of a-EWG-substituted arylmethylphosphonates in high yields.

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