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Aqueous/organic biphasic hydroformylation of 1-octene catalyzed by Co 2 (CO) 8 /Ph 2 P(CH 2 CH 2 O) n Me

✍ Scribed by Wu, Dan; Zhang, Jianwei; Wang, Yanhua; Jiang, Jingyang; Jin, Zilin


Book ID
118752508
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
108 KB
Volume
26
Category
Article
ISSN
0268-2605

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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac